Geochemistry and Sm-Nd systematics of the 1.67 Ga Buanji Group of southwestern Tanzania: Paleo-weathering, provenance and paleo-tectonic setting implications

We present major and trace and Nd-isotopic data of the ∼1.67 Ga Buanji Group of southwestern Tanzania in order to constrain the nature of their protolith and the intensity of chemical weathering in the source terranes and make inferences on the nature of climatic conditions during the late Paleoproterozoic in the region. Major and trace element contents of the shales from three stratigraphic formations are comparable to those of the post-Archaean Australian Shale (PAAS) and the average Proterozoic Shale (PS). They are characterized by enrichments in LREE relative to HREE ((La/Yb)CN = 9.07–13.2; (Gd/Yb)CN = 1.51–1.85) and negative Eu anomalies (Eu/Eu* = 0.61–0.81); features which are comparable to those of PAAS and PS, indicating upper continental sources. Provenance proxy ratios, together with abundances of Cr, Ni, Co and V that increase up-stratigraphy suggest a decreasing input of felsic detritus up-stratigraphy. Chemical Indices of Alteration (CIA) for the lower, middle and upper Buanji formations are 81, 76 and 79, respectively. These indices largely indicate intermediate (ca. 60–80) to extreme (>80) weathering intensities of the precursor rocks. These observations may suggest the prevalence of warm, humid climates during the late Paleoproterozoic in the region.;
The lower Buanji Formation yielded a depleted mantle Nd model age (TDM) of ∼2100 Ma which indicates an Eburnean parentage. TDM ages of 2486–2155 Ma and 2535–2379 Ma obtained from middle and upper Buanji formations, respectively, suggest a progressive increase of sedimentary input from the Tanzania Craton up-stratigraphy. The Eburnean TDM ages of the lower Buanji rocks are attributed to their derivation through denudation of a decaying topographic high composed predominantly of rocks that were generated during the Palaeoproterozoic Ubendian orogenesis, possibly in the realm of Columbian Supercontinent assembly. Overlapping TDM ages between the middle and upper Buanji formations suggest multiple sources involving mixing of detritus from Archaean cratonic rocks and the Palaeoproterozoic Ubendian belt. However, the Archaean signal is relatively more pronounced in the upper Buanji Formation, suggesting sediments derivation from the craton, to the north of the basin. The middle Buanji Formation suggests more diverse protolith, given the relatively larger spread in the TDM ages. The Nb/Ta, Zr/Sm and Ce/Pb ratios coupled with the negative Nb and Ta anomalies, relative to primitive mantle, suggest that the tectonic setting of the source rocks for the Buanji sediments was a subduction zone akin to that generating modern Island Arc Basalts. Thus, we suggest that the Buanji's palaeogeography is consistent with an extensional continental backarc basin during the late Paleoproterozoic.